(1)已知下列各反应的焓变
①Ca(s)+C(s,石墨)+3/2O2(g)=CaCO3(s) △H1 = -1206.8 kJ/mol
②Ca(s)+1/2O2(g)=CaO(s) △H2= -635.1 kJ/mol
③C(s,石墨)+O2(g)=CO2(g) △H3 = -393.5 kJ/mol
试求: ④CaCO3(s)=CaO(s)+CO2(g) △H=________。
(2)已知下列各反应的焓变
①CO(g)+1/2O2(g)=CO2(g) ΔH1= -283.0 kJ/mol
②H2(g)+1/2O2(g)=H2O(l) ΔH2= -285.8 kJ/mol
③C2H5OH(l)+ 3O2(g)=2CO2(g)+3H2O(l) ΔH3=-1370 kJ/mol
试求: ④2CO(g)+4H2(g)=H2O(l)+C2H5OH(l) ΔH=________。